\(\Rightarrow\) (ii): For \(n \geq 1\text{,}\) the segment
\begin{equation*}
\pi_{n+1}(X, A, x_0) = 0 \xrightarrow{\;\partial\;} \pi_n(A, x_0) \xrightarrow{\;i_*\;} \pi_n(X, x_0) \xrightarrow{\;j_*\;} \pi_n(X, A, x_0) = 0
\end{equation*}
shows that \(\ker(i_*) = \operatorname{im}(\partial) = 0\) and \(\operatorname{im}(i_*) = \ker(j_*) = \pi_n(X, x_0)\text{.}\)
(ii) \(\Rightarrow\) (i): Let \(n \geq 1\) and consider
\begin{equation*}
\pi_n(A, x_0) \xrightarrow{\;i_*\;} \pi_n(X, x_0) \xrightarrow{\;j_*\;} \pi_n(X, A, x_0) \xrightarrow{\;\partial\;} \pi_{n-1}(A, x_0) \xrightarrow{\;i_*\;} \pi_{n-1}(X, x_0).
\end{equation*}
Since \(i_*\) is surjective on \(\pi_n\text{,}\) exactness at \(\pi_n(X, x_0)\) gives \(\ker(j_*) = \pi_n(X, x_0)\text{,}\) i.e. \(j_* = 0\text{.}\) Since \(i_*\) is injective on \(\pi_{n-1}\) (for \(n - 1 \geq 1\) by hypothesis, and for \(n - 1 = 0\) because both \(\pi_0(A)\) and \(\pi_0(X)\) are single points), exactness at \(\pi_{n-1}(A, x_0)\) gives \(\operatorname{im}(\partial) = 0\text{,}\) so \(\partial^{-1}(0) = \pi_n(X, A, x_0)\text{.}\) Exactness at \(\pi_n(X, A, x_0)\) then gives \(\pi_n(X, A, x_0) = \partial^{-1}(0) = \operatorname{im}(j_*) = 0\text{.}\)
For the final statement, recall from
Chapter 5 that a homotopy equivalence induces isomorphisms on all homotopy groups, so (ii) holds.